The mineral olivine (also called chrysolite and, when gem-quality, peridot) is a magnesium iron silicate with the formula (Mg,Fe)2SiO4. It is one of the most common minerals on Earth, and has also been identified on the Moon, Mars, and comet Wild 2.
The ratio of magnesium and iron varies between the two endmembers of the solid solution series: forsterite (Mg-endmember) and fayalite (Fe-endmember). Compositions of olivine are commonly expressed as molar percentages of forsterite (Fo) and fayalite (Fa) (e.g., Fo70Fa30). Forsterite has an unusually high melting temperature at atmospheric pressure, almost 1900°C, but the melting temperature of fayalite is much lower (about 1200°C). The melting temperature varies smoothly between the two endmembers, as do other properties.
Olivine gives its name to the group of minerals with a related structure (the olivine group) which includes tephroite (Mn2SiO4), monticellite (CaMgSiO4), and kirschsteinite (CaFeSiO4)
Identification and paragenesis
Olivine is usually named for its typically olive-green color (thought to be a result of traces of nickel), though it may alter to a reddish color from the oxidation of iron. It has a conchoidal fracture and is rather brittle. The hardness of olivine is 6.5–7, its relative density is 3.27–3.37, and it has a vitreous luster. It is transparent to translucent.
Transparent olivine is sometimes used as a gemstone called peridot, the French word for olivine. It is also called chrysolite, from the Greek words for gold and stone. Some of the finest gem-quality olivine has been obtained from a body of mantle rocks on Zabargad island in the Red Sea.
Olivine occurs in both mafic and ultramafic igneous rocks and as a primary mineral in certain metamorphic rocks. Mg-rich olivine crystallizes from magma that is rich in magnesium and low in silica. That magma crystallizes to mafic rocks such as gabbro and basalt. Ultramafic rocks such as peridotite, and dunite can be residues left after extraction of magmas, and typically they are more enriched in olivine after extraction of partial melts. Olivine, or high pressure structural variants, constitute over 50% of the Earth's upper mantle, making it one of the Earth's most common minerals by volume. The metamorphism of impure dolomite or other sedimentary rocks with high magnesium and low silica content also produces Mg-rich olivine, or forsterite.
Fe-rich olivine is relatively much less common, but it occurs in igneous rocks in small amounts in rare granites and rhyolites, and extremely Fe-rich olivine can exist stably with quartz and tridymite. In contrast, Mg-rich olivine does not occur stably with silica minerals, as it would react with them to form orthopyroxene ((Mg,Fe)2Si2O6).
Mg-rich olivine has also been discovered in meteorites, on Mars, and on Earth's moon. Such meteorites include chondrites, collections of debris from the early solar system, and pallasites, mixes of iron-nickel and olivine. The spectral signature of olivine has been seen in the dust disks around young stars. The tails of comets (which formed from the dust disk around the young Sun) often have the spectral signature of olivine, and the presence of olivine has recently been verified in samples of a comet from the Stardust spacecraft.
Minerals in the olivine group crystallize in the orthorhombic system (space group Pbnm) with isolated silicate tetrahedra, meaning that olivine is a nesosilicate. In an alternative view, the atomic structure can be described as a hexagonal, close-packed array of oxygen ions with half of the octahedral sites occupied with magnesium or iron ions and one-eighths of the tetrahedral sites occupied by silicon ions.
There are three distinct oxygen sites (marked O1, O2, and O3 in figure 1), two distinct metal sites (M1 and M2), and only one distinct silicon site. O1, O2, M2, and Si all lie on mirror planes, while M1 exists on an inversion center. O3 lies in a general position.
High pressure polymorphs and phase diagram
At the high temperatures and pressures found at depth within the Earth the olivine structure is no longer stable. Below depths of about 410 km olivine undergoes a phase transition to the sorosilicate, wadsleyite and, at about 520 km depth, wadsleyite transforms into ringwoodite, which has the spinel structure. These phase transitions lead to a discontinuous increase in the density of the Earth's mantle that can be observed by seismic methods.
The pressure at which these phase transitions occur depends on temperature and iron content (Deer et al. 1992). At 800°C the pure magnesium end member, forsterite, transforms to wadsleyite at 11.8 gigapascals (118 kbar) and to ringwoodite at pressures above 14 GPa (140 kbar). Increasing the iron content decreases the pressure of the phase transition and narrows the wadsleyite stability field. At about 0.8 mole fraction fayalite, olivine transforms directly to ringwoodite over the pressure range 10–11.5 GPa (100–115 kbar). Fayalite transforms to Fe2SiO4 spinel at pressures below 5 GPa (50 kbar). Increasing the temperature increases the pressure of these phase transitions.
Historical and mythical uses
According to Rebbenu Bachya, the word "tarshish" in the verse Exodus 28:20 means "chrysolite" and was the stone on the Ephod representing the tribe of Asher.